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A Late Stage Strategy for the Functionalization of Triazolium-based NHC catalysts

A strategy for the diversification of triazolium-based catalysts is presented. This method is based on the reduction to the triazoline, which serves as a suitable and stable substrate for Pd-mediated cross-coupling, followed by trityl cation mediated reoxidation to the triazolium.

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Détails bibliographiques
Publié dans:Synlett
Auteurs principaux: Ozboya, Kerem E., Rovis, Tomislav
Format: Artigo
Langue:Inglês
Publié: 2014
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4419734/
https://ncbi.nlm.nih.gov/pubmed/25954060
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-0034-1379167
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