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Enantioselective Cross-Coupling of meso-Epoxides with Aryl Halides
[Image: see text] The first enantioselective cross-electrophile coupling of aryl bromides with meso-epoxides to form trans-β-arylcycloalkanols is presented. The reaction is catalyzed by a combination of (bpy)NiCl(2) and a chiral titanocene under reducing conditions. Yields range from 57 to 99% with...
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| Gepubliceerd in: | J Am Chem Soc |
|---|---|
| Hoofdauteurs: | , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
American Chemical
Society
2015
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| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4415026/ https://ncbi.nlm.nih.gov/pubmed/25716775 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b01909 |
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