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A Tale of Three Carboxylates: Cooperative Asymmetric Crystallization of Three-Dimensional Microporous Framework from Achiral Precursors
[Image: see text] Chirality Induction in Porous MOF The chiral induction reagent (e.g., D-, L-camphoric acid) exhibits two distinct roles: (1) enable and catalyze growth of chiral crystals, and (2) control bulk chirality of Mn(3)(HCOO)(4)(adc) crystals (H2adc = adamantane-1,3-dicarboxylic acid. Time...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4410852/ https://ncbi.nlm.nih.gov/pubmed/20077556 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.200906248 |
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