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Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis
The routine application of C(sp3)-hybridized nucleophiles in cross-coupling reactions remains an unsolved challenge in organic chemistry. The sluggish transmetalation rates observed for the preferred organoboron reagents in such transformations are a consequence of the two-electron mechanism underly...
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| Published in: | Science |
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| Main Authors: | , , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
2014
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4406487/ https://ncbi.nlm.nih.gov/pubmed/24903560 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.1253647 |
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