Enantioselective Desymmetrization via Carbonyl-Directed Catalytic Asymmetric Hydroboration and Suzuki-Miyaura Cross-Coupling

[Image: see text] The rhodium-catalyzed enantioselective desymmetrization of symmetric γ,δ–unsaturated amides via carbonyl-directed catalytic asymmetric hydroboration (directed CAHB) affords chiral secondary organoboronates with up to 98% ee. The chiral γ–borylated products undergo palladium-catalyz...

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Xehetasun bibliografikoak
Argitaratua izan da:Org Lett
Egile Nagusiak: Hoang, Gia L., Yang, Zhao-Di, Smith, Sean M., Pal, Rhitankar, Miska, Judy L., Pérez, Damaris E., Pelter, Libbie S. W., Zeng, Xiao Cheng, Takacs, James M.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2015
Gaiak:
Article
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC4385711/
https://ncbi.nlm.nih.gov/pubmed/25642639
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol503764d
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