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Enantioselective Desymmetrization via Carbonyl-Directed Catalytic Asymmetric Hydroboration and Suzuki-Miyaura Cross-Coupling
[Image: see text] The rhodium-catalyzed enantioselective desymmetrization of symmetric γ,δ–unsaturated amides via carbonyl-directed catalytic asymmetric hydroboration (directed CAHB) affords chiral secondary organoboronates with up to 98% ee. The chiral γ–borylated products undergo palladium-catalyz...
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| Veröffentlicht in: | Org Lett |
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| Hauptverfasser: | , , , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2015
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4385711/ https://ncbi.nlm.nih.gov/pubmed/25642639 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol503764d |
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