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Synthesis of 3,8-Dichloro-6-ethyl-1,2,5,7-tetramethyl–BODIPY from an Asymmetric Dipyrroketone and Reactivity Studies at the 3,5,8-Positions()

The asymmetric BODIPY 1a (BODIPY=4,4-difluoro-4-bora-3a,4a-diaza-s-indacene), containing two chloro substituents at the 3,8-positions and a reactive 5-methyl group, was synthesized from the asymmetric dipyrroketone 3, which was readily obtained from available pyrrole 2a. The reactivity of 3,8-dichlo...

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Publicat a:Chemistry
Autors principals: Zhao, Ning, Vicente, M. Graça H., Fronczek, Frank R., Smith, Kevin M.
Format: Artigo
Idioma:Inglês
Publicat: 2015
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4382426/
https://ncbi.nlm.nih.gov/pubmed/25761150
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201406550
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