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Polar Effects Control the Gas-phase Reactivity of Charged para-Benzyne Analogs
The gas-phase reactivity of charged para-benzynes is entirely unexplored as they and/or their precursors tend to undergo ring-opening upon their generation. We report here a gas-phase reactivity study of two such benzynes, the 2,5-didehydropyridinium and 5,8-didehydroisoquinolinium cations, generate...
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| Publicado en: | Int J Mass Spectrom |
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| Autores principales: | , , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2014
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4378589/ https://ncbi.nlm.nih.gov/pubmed/25838787 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.ijms.2014.04.017 |
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