Gravar-mail: Total Syntheses and Initial Evaluation of [Ψ[C(=S)NH]Tpg(4)]vancomycin, [Ψ[C(=NH)NH]Tpg(4)]vancomycin, [Ψ[CH(2)NH]Tpg(4)]vancomycin and their (4-Chlorobiphenyl)methyl Derivatives: Synergistic Binding Pocket and Peripheral Modifications for the Glycopeptide Antibiotics