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Mitsunobu mischief: Neighbor-directed histidine N(π)–alkylation provides access to peptides containing selectively functionalized imidazolium heterocycles

There are few methodologies that yield peptides containing His residues with selective N(π), N(π)-bis-alkylated imidazole rings. We have found that, under certain conditions, on-resin Mitsunobu coupling of alcohols with peptides having a N(π)-alkylated His residue results in selective and high-yield...

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Bibliografiske detaljer
Udgivet i:Org Biomol Chem
Main Authors: Qian, Wen-Jian, Burke, Terrence R.
Format: Artigo
Sprog:Inglês
Udgivet: 2015
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4374000/
https://ncbi.nlm.nih.gov/pubmed/25739367
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5ob00171d
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