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Palladium-Mediated Dealkylation of N-Propargyl-Floxuridine as a Bioorthogonal Oxygen-Independent Prodrug Strategy

Herein we report the development and biological screening of a bioorthogonal palladium-labile prodrug of the nucleoside analogue floxuridine, a potent antineoplastic drug used in the clinic to treat advanced cancers. N-propargylation of the N3 position of its uracil ring resulted in a vast reduction...

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Detalhes bibliográficos
Publicado no:Sci Rep
Main Authors: Weiss, Jason T., Carragher, Neil O., Unciti-Broceta, Asier
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4365405/
https://ncbi.nlm.nih.gov/pubmed/25788464
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/srep09329
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