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Structure-Reactivity Relationships of Zwitterionic 1,3-diaza-Claisen Rearrangements
Bridged bicyclic tertiary allylic amines aza-norbornene 1 and isoquinuclidene 2 add to isocyanates, isothiocyanates and in situ-generated carbodiimides to form zwitterionic intermediates that undergo 1,3-diaza-Claisen rearrangements to afford highly substituted ureas, thioureas and guanidines respec...
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| Udgivet i: | J Org Chem |
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| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2013
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4356197/ https://ncbi.nlm.nih.gov/pubmed/24138634 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo401810p |
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