Crystal structure of chlorido­(2-{[2-(4-chloro­phen­yl)hydrazin-1-yl­idene-κN (1)](phen­yl)meth­yl}pyridine-κN)(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III) tetra­phenyl­borate

The title compound, [Ir(η(5)-C(5)Me(5))Cl(C(18)H(14)ClN(3))]B(C(6)H(5))(4), is chiral at the metal center and crystallizes as a racemate. In the cation, the hydrazinyl­idene­pyridine ligand is N,N-coordinated through the N-pyridyl and N-hydrazinyl­idene groups forming a five-membered metallacycle. A...

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Bibliographic Details
Published in:Acta Crystallogr E Crystallogr Commun
Main Authors: Devika, Neelakandan, Raja, Nandhagopal, Ananthalakshmi, Subbiah, Therrien, Bruno
Format: Artigo
Language:Inglês
Published: International Union of Crystallography 2015
Subjects:
Data Reports
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC4350695/
https://ncbi.nlm.nih.gov/pubmed/25844211
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2056989015003023
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