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Study of the Franck-Condon and Herzberg-Teller Approximations

Using the Born-Oppenheimer parameter λ = (m/M)(1/4) as a perturbation parameter, we find that for allowed transitions, the zeroth order approximation of the spectral intensity gives rise to the Condon approximation, the first order vibronic coupling and anharmonic effect appear in the first order ap...

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Detalles Bibliográficos
Publicado en:Proc Natl Acad Sci U S A
Autores principales: Lin, S. H., Eyring, H.
Formato: Artigo
Lenguaje:Inglês
Publicado: National Academy of Sciences 1974
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Acceso en línea:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC434271/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592183/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.71.10.3802
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