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Study of the Franck-Condon and Herzberg-Teller Approximations

Using the Born-Oppenheimer parameter λ = (m/M)(1/4) as a perturbation parameter, we find that for allowed transitions, the zeroth order approximation of the spectral intensity gives rise to the Condon approximation, the first order vibronic coupling and anharmonic effect appear in the first order ap...

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Pubblicato in:Proc Natl Acad Sci U S A
Autori principali: Lin, S. H., Eyring, H.
Natura: Artigo
Lingua:Inglês
Pubblicazione: National Academy of Sciences 1974
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Accesso online:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC434271/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592183/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.71.10.3802
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