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Study of the Franck-Condon and Herzberg-Teller Approximations
Using the Born-Oppenheimer parameter λ = (m/M)(1/4) as a perturbation parameter, we find that for allowed transitions, the zeroth order approximation of the spectral intensity gives rise to the Condon approximation, the first order vibronic coupling and anharmonic effect appear in the first order ap...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
1974
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC434271/ https://ncbi.nlm.nih.gov/pubmed/16592183 |
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