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Ruthenium-catalysed Z-selective cross metathesis of allylic-substituted olefins

The Z-selective cross metathesis of allylic-substituted olefins is explored with recently developed ruthenium-based metathesis catalysts. The reaction proceeds with excellent stereoselectivity for the Z-isomer (typically >95%) and yields of up to 88% for a variety of allylic substituents. This in...

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Bibliografiske detaljer
Udgivet i:Chem Sci
Main Authors: Quigley, Brendan L., Grubbs, Robert H.
Format: Artigo
Sprog:Inglês
Udgivet: Royal Society of Chemistry 2014
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4339074/
https://ncbi.nlm.nih.gov/pubmed/25722847
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c3sc52806e
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