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Nuclear Coupling of (33)S and the Nature of Free Radicals in Irradiated Crystals of Cystine Dihydrochloride: Part II, Charged Radicals
The (33)S hyperfine structure has been observed in negatively charged cystine molecule-radicals RCH(2)(SS)(-)CH(2)R. The coupling, found to be axially symmetric about the SS bond, proved the orbital of the unpaired electron to be an antibonding SS σ(*) orbital with the spin density shared equally be...
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| Hauptverfasser: | , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
1974
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC433894/ https://ncbi.nlm.nih.gov/pubmed/4373715 |
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