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Nuclear Magnetic Resonance Shift Reagents: Abnormal (13)C Shifts Produced by Complexation of Lanthanide Chelates with Saturated Amines and n-Butyl Isocyanide

Lanthanide-induced shfits of (13)C nuclear magnetic resonances are reported for several amines and n-butyl isocyanide. Contact contributions to such shifts, especially of β carbons, are clearly important for the chelates of Eu(+3) and Pr(+3). The importance of contact terms is shown to change in a r...

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Détails bibliographiques
Publié dans:Proc Natl Acad Sci U S A
Auteurs principaux: Marzin, Claude, Leibfritz, Dieter, Hawkes, Geoffrey E., Roberts, John D.
Format: Artigo
Langue:Inglês
Publié: National Academy of Sciences 1973
Sujets:
Accès en ligne:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC433306/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592062/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.70.2.562
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