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Charge disproportionation and the pressure-induced insulator–metal transition in cubic perovskite PbCrO(3)

The perovskite PbCrO(3) is an antiferromagnetic insulator. However, the fundamental interactions leading to the insulating state in this single-valent perovskite are unclear. Moreover, the origin of the unprecedented volume drop observed at a modest pressure of P = 1.6 GPa remains an outstanding pro...

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Veröffentlicht in:Proc Natl Acad Sci U S A
Hauptverfasser: Cheng, Jinguang, Kweon, K. E., Larregola, S. A., Ding, Yang, Shirako, Y., Marshall, L. G., Li, Z.-Y., Li, X., dos Santos, António M., Suchomel, M. R., Matsubayashi, K., Uwatoko, Y., Hwang, G. S., Goodenough, John B., Zhou, J.-S.
Format: Artigo
Sprache:Inglês
Veröffentlicht: National Academy of Sciences 2015
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Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4330739/
https://ncbi.nlm.nih.gov/pubmed/25624483
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1424431112
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