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Iron-sulfur clusters II: Kinetics of ligand exchange studied on a water-soluble Fe(4)S(4)(SR)(4)(n-) cluster

The water-soluble tetranuclear iron-sulfur cluster ion Fe(4)S(4)(SCH(2)CH(2)CO(2)(-))(4)(6-) (II) has been prepared. The stability of II in water is sufficient to allow the spectrotitrimetric determination of the pK(a) of its Fe(4)S(4) core as 7.4. In our hands the one-electron reductions of compoun...

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Sonraí Bibleagrafaíochta
Main Authors: Job, Robert C., Bruice, Thomas C.
Formáid: Artigo
Teanga:Inglês
Foilsithe: 1975
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC432790/
https://ncbi.nlm.nih.gov/pubmed/16592256
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