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Radical mechanisms for 1,5-dihydroflavin reduction of carbonyl compounds.

A discussion of the expected mechanism of radical reduction of carbonyl compounds by dihydroflavin as it relates to the structure of the carbonyl compound is provided. Factors which must be taken into account are the free energies of formation of the radical anions (CR2O), THE ACIDITY OF THE CONJUGA...

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Detalles Bibliográficos
Autores principales: Williams, R F, Shinkai, S, Bruice, T C
Formato: Artigo
Lenguaje:Inglês
Publicado: 1975
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC432626/
https://ncbi.nlm.nih.gov/pubmed/240160
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