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Theory of Rate Processes and the Compensation Rule

The rate of intermolecular charge transfer as involved in the theory of rate processes is derived for a quadratic generalization of Holstein's one-dimensional linear polaron theory. The activation energy and the activation entropy are shown to be proportional to the number of vibrational degrees of...

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Bibliographic Details
Published in:Proc Natl Acad Sci U S A
Main Authors: Kemeny, Gabor, Mahanti, S. D.
Format: Artigo
Language:Inglês
Published: National Academy of Sciences 1975
Subjects:
Online Access:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC432451/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592235/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.72.3.999
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