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Synthesis of α-Diketones from Alkylaryl- and Diarylalkynes Using Mercuric Salts

[Image: see text] Both alkylarylalkynes and diarylalkynes 1 are converted into the α-diketones 2 in good yield by the use of mercuric salts, e.g., mercuric nitrate hydrate or mercuric triflate, in the presence of water. Other mercuric salts, e.g., sulfate, chloride, acetate, or trifluoroacetate, do...

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Détails bibliographiques
Publié dans:Org Lett
Auteurs principaux: Jung, Michael E., Deng, Gang
Format: Artigo
Langue:Inglês
Publié: American Chemical Society 2014
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4316994/
https://ncbi.nlm.nih.gov/pubmed/24684513
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol500592m
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