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Detailed electronic description of triple bonds between transition metal atoms and verification by photoelectron spectroscopy
Using the SCF-Xα-SW method the ground state electronic structures of (HO)(3)Mo≡Mo(OH)(3), (H(2)N)(3)Mo≡Mo(NH(2))(3), and (Me(2)N)(3)Mo≡Mo(NMe(2)) have been calculated. The results provide a detailed description of the metal-to-metal triple bonds present; some of the more important molecular orbitals...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
1977
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC431455/ https://ncbi.nlm.nih.gov/pubmed/16592425 |
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