Fast and Highly Chemoselective Alkynylation of Thiols with Hypervalent Iodine Reagents Enabled through a Low Energy Barrier Concerted Mechanism

[Image: see text] Among all functional groups, alkynes occupy a privileged position in synthetic and medicinal chemistry, chemical biology, and materials science. Thioalkynes, in particular, are highly useful, as they combine the enhanced reactivity of the triple bond with a sulfur atom frequently e...

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Bibliografiske detaljer
Udgivet i:J Am Chem Soc
Main Authors: Frei, Reto, Wodrich, Matthew D., Hari, Durga Prasad, Borin, Pierre-Antoine, Chauvier, Clément, Waser, Jérôme
Format: Artigo
Sprog:Inglês
Udgivet: American Chemical Society 2014
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4311943/
https://ncbi.nlm.nih.gov/pubmed/25365776
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja5083014
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