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Gold(I)-Catalyzed Intermolecular Cycloaddition of Allenamides with α,β-Unsaturated Hydrazones: Efficient Access to Highly Substituted Cyclobutanes

[Image: see text] α,β-Unsaturated N,N-dialkyl hydrazones undergo a mild [2 + 2] cycloaddition to allenamides when treated with a suitable gold catalyst. The method, which represents the first application of N,N-dialkyl hydrazones in gold catalysis, is compatible with a wide variety of substituents a...

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Détails bibliographiques
Publié dans:Org Lett
Auteurs principaux: Bernal-Albert, Paloma, Faustino, Hélio, Gimeno, Ana, Asensio, Gregorio, Mascareñas, José L., López, Fernando
Format: Artigo
Langue:Inglês
Publié: American Chemical Society 2014
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4304836/
https://ncbi.nlm.nih.gov/pubmed/25406491
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol503121q
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