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Kinetics and mechanism of the reaction of hydrogen sulfide with diaquacobinamide in aqueous solution
We conducted a detailed kinetic study of the reaction of the vitamin B(12) analog diaquacobinamide ((H(2)O)(2)Cbi(III)) with hydrogen sulfide in water from pH 3 to 11. The reaction proceeds in three steps: (i) formation of three different complexes between cobinamide and hydrogen sulfide, viz. (HO(−...
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| Publicado no: | Eur J Inorg Chem |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4286256/ https://ncbi.nlm.nih.gov/pubmed/25580081 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.201402082 |
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