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Multiple light-induced NO linkage isomers in the dinitrosyl complex [RuCl(NO)(2)(PPh(3))(2)]BF(4) unravelled by photocrystallographic and IR analysis

Multiple light-induced reversible metastable NO linkage isomers (PLIs) have been detected in the dinitrosyl compound [RuCl(NO)(2)(PPh(3))(2)]BF(4) by a combination of photocrystallographic and IR analysis. The IR signature of three PLI states has been clearly identified, with estimated populations o...

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Détails bibliographiques
Publié dans:IUCrJ
Auteurs principaux: Casaretto, Nicolas, Pillet, Sebastien, Bendeif, El Eulmi, Schaniel, Dominik, Gallien, Anna K. E., Klüfers, Peter, Woike, Theo
Format: Artigo
Langue:Inglês
Publié: International Union of Crystallography 2015
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4285879/
https://ncbi.nlm.nih.gov/pubmed/25610626
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2052252514023598
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