Sterically Demanding Unsymmetrical Diaryl-λ(3)-iodanes for Electrophilic Pentafluorophenylation and an Approach to α-Pentafluorophenyl Carbonyl Compounds with an All-Carbon Stereocenter

A sterically demanding unsymmetrical pentafluorophenyl-triisopropylphenyl-λ(3)-iodane was developed as an effective reagent for the electrophilic pentafluorophenylation of various β-keto esters and a β-keto amide. 17 examples of α-pentafluorophenylated 1,3-dicarbonyl compounds 3 having a quaternary...

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Detalhes bibliográficos
Publicado no:ChemistryOpen
Main Authors: Matsuzaki, Kohei, Okuyama, Kenta, Tokunaga, Etsuko, Shiro, Motoo, Shibata, Norio
Formato: Artigo
Idioma:Inglês
Publicado em: Blackwell Publishing Ltd 2014
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4280821/
https://ncbi.nlm.nih.gov/pubmed/25558441
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/open.201402045
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