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Energetics of metastudtite and implications for nuclear waste alteration

Metastudtite, (UO(2))O(2)(H(2)O)(2), is one of two known natural peroxide minerals, but little is established about its thermodynamic stability. In this work, its standard enthalpy of formation, −1,779.6 ± 1.9 kJ/mol, was obtained by high temperature oxide melt drop solution calorimetry. Decompositi...

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Detalhes bibliográficos
Publicado no:Proc Natl Acad Sci U S A
Main Authors: Guo, Xiaofeng, Ushakov, Sergey V., Labs, Sabrina, Curtius, Hildegard, Bosbach, Dirk, Navrotsky, Alexandra
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4273415/
https://ncbi.nlm.nih.gov/pubmed/25422465
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1421144111
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