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Organic chemistry on surfaces: Direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs)

C11-Vinyl-terminated self-assembled monolayers (SAMs) on silica surfaces are successfully modified in C–C bond forming reactions with dihalocarbenes to generate SAMs, terminated with dihalo- (fluoro, chloro, bromo) cyclopropane motifs with about 30% surface coverage.

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書目詳細資料
發表在:Beilstein J Org Chem
Main Authors: Adamkiewicz, Malgorzata, O’Hagan, David, Hähner, Georg
格式: Artigo
語言:Inglês
出版: Beilstein-Institut 2014
主題:
在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC4273226/
https://ncbi.nlm.nih.gov/pubmed/25550756
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.10.307
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