Anomalously large isotope effect in the glass transition of water

We present the discovery of an unusually large isotope effect in the structural relaxation and the glass transition temperature T(g) of water. Dielectric relaxation spectroscopy of low-density as well as of vapor-deposited amorphous water reveal T(g) differences of 10 ± 2 K between H(2)O and D(2)O,...

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Detaylı Bibliyografya
Yayımlandı:Proc Natl Acad Sci U S A
Asıl Yazarlar: Gainaru, Catalin, Agapov, Alexander L., Fuentes-Landete, Violeta, Amann-Winkel, Katrin, Nelson, Helge, Köster, Karsten W., Kolesnikov, Alexander I., Novikov, Vladimir N., Richert, Ranko, Böhmer, Roland, Loerting, Thomas, Sokolov, Alexei P.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: National Academy of Sciences 2014
Konular:
Physical Sciences
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC4267340/
https://ncbi.nlm.nih.gov/pubmed/25422420
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1411620111
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