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Rapid synthesis of 1,7-bis(t-butoxycarbonylmethyl)-1,4,7,10-tetraazacyclododecane (DO2A-t-Bu ester)

A three-step route was used to synthesize 1,7-bis(t-butoxycarbonylmethyl)-1,4,7,10-tetraazacyclododecane (DO2A-t-Bu ester) from 1,4,7,10-tetraazacyclododecane (cyclen). The overall time of reaction was reduced from a combined ~56 h to 2.3 h with an overall yield comparable to previously reported met...

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Detalhes bibliográficos
Publicado no:Tetrahedron Lett
Main Authors: Hopper, Lauren E., Allen, Matthew J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4261951/
https://ncbi.nlm.nih.gov/pubmed/25506095
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2014.08.026
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