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Metal-Free Dihydrogen Oxidation by a Borenium Cation: A Combined Electrochemical/Frustrated Lewis Pair Approach**
In order to use H(2) as a clean source of electricity, prohibitively rare and expensive precious metal electrocatalysts, such as Pt, are often used to overcome the large oxidative voltage required to convert H(2) into 2 H(+) and 2 e(−). Herein, we report a metal-free approach to catalyze the oxidati...
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| 發表在: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
WILEY-VCH Verlag
2014
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4257500/ https://ncbi.nlm.nih.gov/pubmed/25044562 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201405721 |
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