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Crystal structures of 3,6-diallyltetracyclo[6.3.0.0(4,11).0(5,9)]undeca-2,7-dione and 1,7-diallylpentacyclo[5.4.0.0(2,6). 0(3,10).0(5,9)]undecane-8,11-dione: allylated caged compounds
The title compounds, C(17)H(20)O(2) (1) and C(17)H(18)O(2) (2), are allylated caged compounds. In (1), the carbon atoms bearing the allyl groups are far apart [2.9417 (17) Å], hence the expected ring-closing metathesis (RCM) protocol failed to give a ring-closing product. When these carbon atoms ar...
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| Udgivet i: | Acta Crystallogr Sect E Struct Rep Online |
|---|---|
| Main Authors: | , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
International Union of Crystallography
2014
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4257271/ https://ncbi.nlm.nih.gov/pubmed/25484760 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1600536814023149 |
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