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Z-Selective Ruthenium Metathesis Catalysts: Comparison of Nitrate and Nitrite X-type Ligands

Two new Ru-based metathesis catalysts, 3 and 4, have been synthesized for the purpose of comparing their catalytic properties to those of their cis-selective nitrate analogues, 1 and 2. Although catalysts 3 and 4 exhibited slower initiation rates than 1 and 2, they maintained high cis-selectivity in...

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Detalhes bibliográficos
Publicado no:Polyhedron
Main Authors: Pribisko, Melanie A., Ahmed, Tonia S., Grubbs, Robert H.
Formato: Artigo
Idioma:Inglês
Publicado em: 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4254782/
https://ncbi.nlm.nih.gov/pubmed/25484484
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.poly.2014.06.055
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