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Photoassisted Diversity-Oriented Synthesis: Accessing 2,6-Epoxyazocane (Oxamorphan) Cores

[Image: see text] The modular synthesis of photoprecursors and their photoinduced cyclization into substituted 1-benzazocanes of two distinct topologies is described. The key step producing an extended polyheterocyclic system involves the photogeneration of azaxylylenes and their subsequent intramol...

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Detalhes bibliográficos
Publicado no:J Org Chem
Main Authors: Mukhina, Olga A., Kumar, N. N. Bhuvan, Cowger, Teresa M., Kutateladze, Andrei G.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4242042/
https://ncbi.nlm.nih.gov/pubmed/25370821
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo5019848
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