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Small molecule solvation changes due to the presence of salt are governed by the cost of solvent cavity formation and dispersion

We are interested in the free energies of transferring nonpolar solutes into aqueous NaCl solutions with salt concentrations upwards of 2 M, the Hofmeister regime. We use the semi-explicit assembly (SEA) computational model to represent these electrolyte solutions. We find good agreement with experi...

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Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:J Chem Phys
Egile Nagusiak: Li, Libo, Fennell, Christopher J., Dill, Ken A.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: American Institute of Physics 2014
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC4241710/
https://ncbi.nlm.nih.gov/pubmed/25494789
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.4900890
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