Merging Gold and Organocatalysis: A Facile Asymmetric Synthesis of Annulated Pyrroles

The combination of cinchona-alkaloid-derived primary amine and Au(I)–phosphine catalysts allowed the selective C—H functionalization of two adjacent carbon atoms of pyrroles under mild reaction conditions. This sequential dual activation provides seven-membered-ring-annulated pyrrole derivatives in...

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Publicat a:Chemistry
Autors principals: Hack, Daniel, Loh, Charles C J, Hartmann, Jan M, Raabe, Gerhard, Enders, Dieter
Format: Artigo
Idioma:Inglês
Publicat: WILEY-VCH Verlag 2014
Matèries:
Communications
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4238261/
https://ncbi.nlm.nih.gov/pubmed/24590817
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201400407
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