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Quantification of Electrophilic Activation by Hydrogen-Bonding Organocatalysts
[Image: see text] A spectrophotometric sensor is described that provides a useful assessment of the LUMO-lowering provided by catalysts in Diels–Alder and Friedel–Crafts reactions. A broad range of 33 hydrogen-bonding catalysts was assessed with the sensor, and the relative rates in the above reacti...
Guardat en:
| Publicat a: | J Am Chem Soc |
|---|---|
| Autors principals: | , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
American Chemical
Society
2014
|
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4235367/ https://ncbi.nlm.nih.gov/pubmed/25325850 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja5086244 |
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