The Iron–Sulfur Cluster of Pyruvate Formate-Lyase Activating Enzyme in Whole Cells: Cluster Interconversion and a Valence-Localized [4Fe-4S](2+) State()

Pyruvate formate-lyase activating enzyme (PFL-AE) catalyzes the generation of a catalytically essential glycyl radical on pyruvate formate-lyase (PFL). Purified PFL-AE contains an oxygen-sensitive, labile [4Fe-4S] cluster that undergoes cluster interconversions in vitro, with only the [4Fe-4S](+) cl...

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Publicado en:Biochemistry
Autores principales: Yang, Jian, Naik, Sunil G., Ortillo, Danilo O., García-Serres, Ricardo, Li, Meng, Broderick, William E., Huynh, Boi Hanh, Broderick, Joan B.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2009
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Article
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC4230446/
https://ncbi.nlm.nih.gov/pubmed/19711960
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi9010286
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