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Enantioselective Intramolecular C–H Insertion Reactions of Donor–Donor Metal Carbenoids

[Image: see text] The first asymmetric insertion reactions of donor–donor carbenoids, i.e., those with no pendant electron-withdrawing groups, are reported. This process enables the synthesis of densely substituted benzodihydrofurans with high levels of enantio- and diastereoselectivity. Preliminary...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Soldi, Cristian, Lamb, Kellan N., Squitieri, Richard A., González-López, Marcos, Di Maso, Michael J., Shaw, Jared T.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4227726/
https://ncbi.nlm.nih.gov/pubmed/25308822
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja508586t
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