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Dynamical traps lead to the slowing down of intramolecular vibrational energy flow
The phenomenon of intramolecular vibrational energy redistribution (IVR) is at the heart of chemical reaction dynamics. Statistical rate theories, assuming instantaneous IVR, predict exponential decay of the population with the properties of the transition state essentially determining the mechanism...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
National Academy of Sciences
2014
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4209979/ https://ncbi.nlm.nih.gov/pubmed/25246538 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1406630111 |
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