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A Group of Sequence-Related Sphingomonad Enzymes Catalyzes Cleavage of β-Aryl Ether Linkages in Lignin β-Guaiacyl and β-Syringyl Ether Dimers

[Image: see text] Lignin biosynthesis occurs via radical coupling of guaiacyl and syringyl hydroxycinnamyl alcohol monomers (i.e., “monolignols”) through chemical condensation with the growing lignin polymer. With each chain-extension step, monolignols invariably couple at their β-positions, generat...

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Auteurs principaux: Gall, Daniel L., Ralph, John, Donohue, Timothy J., Noguera, Daniel R.
Format: Artigo
Langue:Inglês
Publié: American Chemical Society 2014
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4207535/
https://ncbi.nlm.nih.gov/pubmed/25232892
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/es503886d
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