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A Radical Intermediate in the Conversion of Pentachlorophenol to Tetrachlorohydroquinone by Sphingobium chlorophenolicum
[Image: see text] Pentachlorophenol (PCP) hydroxylase, the first enzyme in the pathway for degradation of PCP in Sphingobium chlorophenolicum, is an unusually slow flavin-dependent monooxygenase (k(cat) = 0.02 s(–1)) that converts PCP to a highly reactive product, tetrachlorobenzoquinone (TCBQ). Usi...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American
Chemical Society
2014
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4204890/ https://ncbi.nlm.nih.gov/pubmed/25238136 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi5010427 |
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