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Iron(II) Complexes Supported by Sulfonamido Tripodal Ligands: Endogenous versus Exogenous Substrate Oxidation

[Image: see text] High-valent iron species are known to act as powerful oxidants in both natural and synthetic systems. While biological enzymes have evolved to prevent self-oxidation by these highly reactive species, development of organic ligand frameworks that are capable of supporting a high-val...

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Main Authors: Cook, Sarah A., Ziller, Joseph W., Borovik, A. S.
פורמט: Artigo
שפה:Inglês
יצא לאור: American Chemical Society 2014
גישה מקוונת:https://ncbi.nlm.nih.gov/pmc/articles/PMC4203402/
https://ncbi.nlm.nih.gov/pubmed/25264932
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic501531g
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