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Site-Selective Catalysis of Phenyl Thionoformate Transfer as a Tool for Regioselective Deoxygenation of Polyols

We report the application of peptide-embedded imidazoles as catalysts for the site-selective delivery of the phenyl thionoformate unit as a prelude to deoxygenation reactions of polyols. Methodology was developed that allows for the synthesis of thiocarbonyl derivatives based on a combination of add...

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Main Authors: Sánchez-Roselló, María, Puchlopek, Angela L. A., Morgan, Adam J., Miller, Scott J.
Format: Artigo
Jezik:Inglês
Izdano: 2008
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC4189089/
https://ncbi.nlm.nih.gov/pubmed/18229939
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo702334z
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