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Vicinal Diamination of Alkenes under Rh-Catalysis

[Image: see text] The synthesis of 1,2-diamines has been achieved through a single-step, tandem sequence involving Rh-catalyzed aziridination followed by NaI-promoted rearrangement to an isomeric cyclic sulfamide. Facile ring opening of these products in hot water and pyridine affords differentially...

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Autori principali: Olson, David E., Su, Justin Y., Roberts, D. Allen, Du Bois, J.
Natura: Artigo
Lingua:Inglês
Pubblicazione: American Chemical Society 2014
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4183635/
https://ncbi.nlm.nih.gov/pubmed/25233140
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja506532h
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