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Polymer collapse in miscible good solvents is a generic phenomenon driven by preferential adsorption

Water and alcohol, such as methanol or ethanol, are miscible and, individually, good solvents for poly(N-isopropylacrylamide) (PNIPAm), but this polymer precipitates in water–alcohol mixtures. The intriguing behaviour of solvent mixtures that cannot dissolve a given polymer or a given protein, while...

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Detalhes bibliográficos
Main Authors: Mukherji, Debashish, Marques, Carlos M., Kremer, Kurt
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Pub. Group 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4175582/
https://ncbi.nlm.nih.gov/pubmed/25216245
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms5882
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