Chargement en cours...
Reaction of selected carbohydrate aldehydes with benzylmagnesium halides: benzyl versus o-tolyl rearrangement
The Grignard reaction of 2,3-O-isopropylidene-α-D-lyxo-pentodialdo-1,4-furanoside and benzylmagnesium chloride (or bromide) afforded a non-separable mixture of diastereomeric benzyl carbinols and diastereomeric o-tolyl carbinols. The latter resulted from an unexpected benzyl to o-tolyl rearrangement...
Enregistré dans:
| Auteurs principaux: | , , , |
|---|---|
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
Beilstein-Institut
2014
|
| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4168906/ https://ncbi.nlm.nih.gov/pubmed/25246953 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.10.202 |
| Tags: |
Ajouter un tag
Pas de tags, Soyez le premier à ajouter un tag!
|