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Accurate measurement of heteronuclear dipolar couplings by phase-alternating R-symmetry (PARS) sequences in magic angle spinning NMR spectroscopy

We report a Phase-Alternating R-Symmetry (PARS) dipolar recoupling scheme for accurate measurement of heteronuclear (1)H-X (X = (13)C, (15)N, (31)P, etc.) dipolar couplings in MAS NMR experiments. It is an improvement of conventional C- and R-symmetry type DIPSHIFT experiments where, in addition to...

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Detalhes bibliográficos
Main Authors: Hou, Guangjin, Lu, Xingyu, Vega, Alexander J., Polenova, Tatyana
Formato: Artigo
Idioma:Inglês
Publicado em: American Institute of Physics 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4162908/
https://ncbi.nlm.nih.gov/pubmed/25217909
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.4894226
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